A study on vibrational energy in H2O produced in the reaction of OH with cyclohexane

被引:0
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作者
Dulamita, N
Simianu, V
Maicaneanu, A
机构
[1] Univ Babes Bolyai, Dept Chem Technol, R-3400 Cluj Napoca, Romania
[2] Marquette Univ, Dept Chem, Milwaukee, WI 53233 USA
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Time-resolved infrared absorption/gain spectroscopy has been applied to the study of vibrational energy disposal dynamics of the reaction of OH with cyclohexane. An optical gain in IR has been obtained thanks to the population inversion for 000-010, 010-020, 010-100 and 010-001 water transitions. A rotational temperature of 600 K for 010-020 and 900 K for 000-010 vibrational transitions were found using out an original computation method.
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页码:343 / 348
页数:6
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