Chromatographic separation of In(III) from Cd(II) in aqueous solutions using commercial resin (Dowex 50W-X8)

被引:14
|
作者
Massoud, Ayman [1 ]
Abou El-Nour, F. [2 ]
Killa, H. [3 ]
Seddik, U. [1 ]
机构
[1] Egyptian Atom Energy Author, Nucl Res Ctr, Cyclotron Facil, Cairo, Egypt
[2] Egyptian Atom Energy Author, Nuclear Chem Dept, Cairo, Egypt
[3] Zagazig Univ, Fac Sci, Dept Chem, Zagazig, Egypt
来源
关键词
Separation of indium and cadmium; Dowex; 50w-x8; SOLVENT-EXTRACTION; HYDROCHLORIC-ACID; ACRYLIC-ACID; INDIUM III; ADSORPTION; PRECONCENTRATION; RECOVERY; GA(III); MEDIA;
D O I
10.2478/s11532-010-0041-z
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This work assesses the potential of an adsorptive material, Dowex 50w-x8, for the separation of indium ions from cadmium ions in aqueous media. The adsorption behavior of Dowex 50 w-x8 for indium and cadmium ions was investigated. The effect of pH, initial concentration of metal ions, the weight of resins, and contact time on the sorption of each of the metal ions were determined. It was found that the adsorption percentage of the indium ions was more than 99% at pH 4.0. The result shows that In (III) was most strongly extracted, while Cd(II) was slightly extracted at this pH value. The recovery of In(III) and Cd(II) ions is around 98% using hydrochloric acid as the best eluent.
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页码:696 / 701
页数:6
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