Rhodium(I) Complexes of Tridentate N-Donor Ligands and Their Supramolecular Assembly Studies

被引：24
|
作者：
Chan, Alan Kwun-Wa
Wu, Di
Wong, Keith Man-Chung [1 ,2 ]
Yam, Vivian Wing-Wah [1 ]
机构：
[1] Univ Hong Kong, Inst Mol Funct Mat, Areas Excellence Scheme, Univ Grants Comm, Pokfulam Rd, Hong Kong, Hong Kong, Peoples R China
[2] South Univ Sci & Technol China, Dept Chem, 1088 Tangchang Blvd, Shenzhen, Guangdong, Peoples R China
来源：
INORGANIC CHEMISTRY | 2016年 / 55卷 / 07期
关键词：
LUMINESCENT; NANOWIRES; COORDINATION; AGGREGATION; DINUCLEAR; OLIGOMERS; POLYMER; PLANAR; STATE;
D O I：
10.1021/acs.inorgchem.6b00289
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New classes of tridentate N-donor rhodium(I) complexes have been synthesized and demonstrated to exhibit interesting induced self-assembly behavior by variation of external stimuli, as a result of extensive Rh(I)center dot center dot center dot Rh(I) interactions, with the assistance of pi-pi stacking and hydrophobic-hydrophobic interactions. An isodesmic aggregation mechanism has also been identified in the temperature dependent process. Upon aggregation in acetone solution, the complex molecules form wire-like nanostructures with their shape dependent on the pi-conjugation of the tridentate ligands. On the other hand, crystalline needles of rhodium(I) complexes obtained from recrystallization have also been shown to exhibit conductivity on the order of 10(-3) S cm(-1).
引用
收藏
页码：3685 / 3691
页数：7
相关论文
共 50 条
  • [1] CATIONIC RHODIUM(I) THIOCARBONYL COMPLEXES WITH TRIPHENYLPHOSPHINE AND N-DONOR LIGANDS
    USON, R
    LAHUERTA, P
    CARMONA, D
    ORO, LA
    HILDENBRAND, K
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 157 (01) : 63 - 67
  • [2] Dinuclear rhodium(II) pivalate complexes with N-donor ligands
    A. A. Sidorov
    G. G. Aleksandrov
    E. V. Pakhmutova
    A. Yu. Chernyad ‘ev
    I. L. Eremenko
    I. I. Moiseev
    [J]. Russian Chemical Bulletin, 2005, 54 : 588 - 599
  • [3] Dinuclear rhodium(II) pivalate complexes with N-donor ligands
    Sidorov, AA
    Aleksandrov, GG
    Pakhmutova, EV
    Chernyad'ev, AY
    Eremenko, IL
    Moiseev, II
    [J]. RUSSIAN CHEMICAL BULLETIN, 2005, 54 (03) : 588 - 599
  • [4] Syntheses, characterization, and reactivity of copper complexes with tridentate N-donor ligands
    Astner, Joerg
    Weitzer, Markus
    Foxon, Simon P.
    Schindler, Siegfried
    Heinemann, Frank W.
    Mukherjee, Jhumpa
    Gupta, Rajeev
    Mahadevan, Viswanath
    Mukherjee, Rabindranath
    [J]. INORGANICA CHIMICA ACTA, 2008, 361 (01) : 279 - 292
  • [5] Computational thermodynamic study on the complexes of Am(III) with tridentate N-donor ligands
    Liang, Yan-Ni
    Yang, Xia
    Ding, Songdong
    Li, Shoujian
    Wang, Fan
    Chai, Zhifang
    Wang, Dongqi
    [J]. NEW JOURNAL OF CHEMISTRY, 2015, 39 (10) : 7716 - 7729
  • [6] Intramolecular substitution reaction of cis-dicarbonyl rhodium(I) complexes containing tridentate N-donor ligand
    Zhang, SF
    Qian, QL
    Chen, Y
    Yuan, GQ
    [J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2004, 25 (11): : 2019 - 2023
  • [7] Intramolecular Hydroamination of Aminoalkenes using Rhodium(I) and Iridium(I) Complexes with N,N- and P,N-Donor Ligands
    Nguyen, Thi O.
    Man, Bradley Y-W.
    Hodgson, Richard
    Messerle, Barbara A.
    [J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 2011, 64 (06) : 741 - 746
  • [8] Synthesis and electron paramagnetic resonance studies of seven coordinated Mn(II) complexes with tridentate N-donor ligands
    Lazarou, Katerina N.
    Stamatopoulos, Ioannis
    Psycharis, Vassilis
    Duboc, Carole
    Raptopoulou, Catherine P.
    Sanakis, Yiannis
    [J]. POLYHEDRON, 2018, 155 : 291 - 301
  • [9] Metal Complexes with N-donor Ligands
    Kotai, Laszlo
    [J]. INORGANICS, 2024, 12 (05)
  • [10] Yttrium complexes with N-donor ligands
    Petrosyants, S. P.
    Ilyukhin, A. B.
    [J]. RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2014, 40 (11) : 825 - 830
12345