Synthesis of π-conjugated polymers bearing electronic and optical functionalities by organometallic polycondensations.: Chemical properties and applications of the π-conjugated polymers

被引：104

作者：

Yamamoto, T ^{[1
]}

机构：

[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

SYNLETT | 2003年 / 04期

关键词：

pi-conjugated polymers; organometallic polycondensation; redox reaction; devices; catalysis;

D O I：

10.1055/s-2003-37504

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Various pi-conjugated polymers have been obtained by using organometallic polycondensations mediated by organotransition metal complexes. For example, Ni(0) complex-promoted dehalogenation polycondensation of dihaloaromatic compounds X-Ar-X affords poly(arylene)s, -(-Ar-)-(n). Pd-catalyzed polycondensation gives poly(arylene- ethynylene)s, -(-Ar-CdropC-Ar'-CdropC-)-(n). These polymers are electrochemically active, electrically conductive, and light-emitting. Their well-characterized linear structure brings about unique packing of the polymer molecules in the solid. In this review, we report their synthesis by organometallic polycondensations, their basic properties, the ordered structure in the solid, and applications for electronic and optical devices of pi-conjugated polymers.

引用

页码：425 / 450

页数：26

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