A pcu-type metal-organic framework with spindle [Zn7(OH)8]6+ cluster as secondary building units

被引：208
|
作者：
Li, Jian-Rong [1 ]
Tao, Ying [1 ]
Yu, Qun [1 ]
Bu, Xian-He [1 ]
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2007年 / 15期
关键词：
D O I：
10.1039/b615675d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The in situ solvothermal reaction of 9,10-dicyanoanthracene and ZnCl2/NaN3 gave the complex, {[Zn-7(OH)(8)(DTA)(3)](H2O)-H-.}(n) (1) (DTA(2-) = 9,10-ditetrazolateanthracene), which presents a pcu- type topological framework formed by DTA(2-) bridging unprecedented heptanuclear spindle [Zn-7(OH)(8)](6+) clusters as SBUs, and exhibits strong luminescent emission with long lifetime.
引用
收藏
页码：1527 / 1529
页数：3
相关论文
共 50 条
  • [1] Photochromism and photoswitchable luminescence in a Zn7 cluster-based metal-organic framework with an organic guest
    Liu, Jian-Jun
    Fu, Jia-Jia
    Liu, Teng
    He, Chi-Xian
    Cheng, Feixiang
    [J]. DALTON TRANSACTIONS, 2021, 50 (46) : 17023 - 17028
  • [2] Unusual Zn5(μ3-OH)2(COO-)8 secondary building units for the construction of a metal-organic framework
    Yang, Hui
    Li, Tie Hu
    Kang, Yao
    Wang, Fei
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 25 : 92 - 95
  • [3] A pcu-type metal-organic framework based on covalently quadruple cross-linked supramolecular building blocks (SBBs): structure and adsorption properties
    Li, Chuanqiang
    Qiu, Wenge
    Shi, Wei
    Song, Haibin
    Bai, Guangmei
    He, Hong
    Li, Jian
    Zaworotko, Michael J.
    [J]. CRYSTENGCOMM, 2012, 14 (06): : 1929 - 1932
  • [4] Unusual [Cd3IIO2(CO2)8] clusters as SBUs for the construction of a new pcu-type metal-organic framework
    Chen, Yan-Fei
    Zhang, Hua-Bin
    Chen, Shu-Mei
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2013, 38 : 11 - 13
  • [5] A New Metal-Organic Framework with Pentanuclear Zinc Clusters as Secondary Building Units
    Xue, Xiaofei
    Liu, Yuqi
    Liu, Qiang
    Wang, Xinying
    Li, Wei
    Peng, Jinhui
    [J]. JOURNAL OF CLUSTER SCIENCE, 2018, 29 (04) : 625 - 632
  • [6] A Zn( II) metal-organic framework with dinuclear [Zn2(N-oxide)2] secondary building units
    Ochi, Rika
    Noro, Shin-ichiro
    Kubo, Kazuya
    Nakamura, Takayoshi
    [J]. DALTON TRANSACTIONS, 2019, 48 (19) : 6314 - 6318
  • [7] An acs-Type Metal-Organic Framework with an Unprecedented Undecanuclear Copper Cluster as Secondary Building Unit
    Hu, Sheng
    Yu, Fang-Yong
    Zhang, Peng
    Zhou, Ai-Ju
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2012, (23) : 3669 - 3673
  • [8] Metal-organic frameworks of linear trinuclear cluster secondary building units: structures and applications
    Chao, Meng-Yao
    Li, Qing
    Zhang, Wen-Hua
    Young, David J.
    [J]. DALTON TRANSACTIONS, 2021, 50 (36) : 12692 - 12707
  • [9] A Homochiral Multifunctional Metal-Organic Framework with Rod-Shaped Secondary Building Units
    Cai, Kun
    Zhao, Nian
    Zhang, Ning
    Sun, Fu-Xing
    Zhao, Qing
    Zhu, Guang-Shan
    [J]. NANOMATERIALS, 2017, 7 (04):
  • [10] A new open metal-organic framework [Zn8(GeO4)(C8H4O4)6]n, constructed by heterometallic cluster Zn8(GeO4) secondary building units
    Chen, JX
    Liu, ZC
    Yu, T
    Chen, ZX
    Sun, JY
    Weng, LH
    Tu, B
    Zhao, DY
    [J]. CHEMISTRY LETTERS, 2003, 32 (05) : 474 - 475
12345