Confined polydiacetylene polymerization reactions for programmed length control

被引：21
|
作者：
Verstraete, Lander [1 ]
Hirsch, Brandon E. [1 ]
Greenwood, John [1 ]
De Feyter, Steven [1 ]
机构：
[1] Univ Leuven, KU Leuven, Dept Chem, Div Mol Imaging & Photon, Celestijnenlaan 200F, B-3001 Leuven, Belgium
来源：
CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 30期
基金：
欧洲研究理事会;
关键词：
SCANNING PROBE LITHOGRAPHY; SELF-ASSEMBLED MONOLAYERS; COVALENT MODIFICATION; CHAIN POLYMERIZATION; BUILDING-BLOCKS; STM-TIP; SURFACE; CHEMISTRY; POLYMERS; NANOSTRUCTURES;
D O I：
10.1039/c7cc00885f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Polydiacetylene polymers of defined lengths are formed from selfassembled precursors inside nanocorrals created within grafted graphite substrates. A scanning tunneling microscope tip is used to nanoshave corrals at the liquid-solid interface allowing orientationally controlled supramolecular self-assembly of linear diacetylene molecules. Electrical pulses trigger topological one-dimensional polymerization reactions that are confined by the nanocorral template dimensions.
引用
收藏
页码：4207 / 4210
页数：4
相关论文
共 50 条
  • [1] TEMPERATURE CONTROL OF POLYMERIZATION REACTIONS
    LABARRE, EE
    TURNER, DT
    [J]. JOURNAL OF DENTAL RESEARCH, 1981, 60 : 440 - 440
  • [2] Sensitivity Enhancement of Polydiacetylene Vesicles through Control of Particle Size and Polymerization Temperature
    Lee, Gil Sun
    Oh, Jae Ho
    Ahn, Dong June
    [J]. KOREAN CHEMICAL ENGINEERING RESEARCH, 2011, 49 (04): : 400 - 404
  • [3] Two-Photon Polymerization of Polydiacetylene
    Shusterman, Olga
    Berman, Amir
    Golan, Yuval
    Horovitz, Baruch
    Zeiri, Leila
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2009, 113 (05): : 1273 - 1276
  • [4] Increasing PVC suspension polymerization productivity using temperature programmed reactions
    Longeway, GD
    Witenhafer, DE
    [J]. ANTEC 2000: SOCIETY OF PLASTICS ENGINEERS TECHNICAL PAPERS, CONFERENCE PROCEEDINGS, VOLS I-III, 2000, : 3415 - 3418
  • [5] Using fluorescence anisotropy to monitor catalytic polymerization reactions confined in droplets
    Cavell, Andrew
    Krasecki, Veronica
    Goldsmith, Randall
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 257
  • [6] Effect of alkyl chain length on chemical sensing of polydiacetylene and polydiacetylene/ZnO nanocomposites
    Aide Wu
    Yuan Gu
    Huiquan Tian
    John F. Federici
    Zafar Iqbal
    [J]. Colloid and Polymer Science, 2014, 292 : 3137 - 3146
  • [7] Effect of alkyl chain length on chemical sensing of polydiacetylene and polydiacetylene/ZnO nanocomposites
    Wu, Aide
    Gu, Yuan
    Tian, Huiquan
    Federici, John F.
    Iqbal, Zafar
    [J]. COLLOID AND POLYMER SCIENCE, 2014, 292 (12) : 3137 - 3146
  • [8] Increasing PVC suspension polymerization productivity by using temperature-programmed reactions
    Longeway, GD
    Witenhafer, DE
    [J]. JOURNAL OF VINYL & ADDITIVE TECHNOLOGY, 2000, 6 (02): : 100 - 103
  • [9] Polymerization Temperature-dependent Thermochromism of Polydiacetylene
    Jeon, Seongho
    Yoon, Bora
    Kim, Jong-Man
    [J]. BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2015, 36 (08) : 1949 - 1950
  • [10] MODEL REACTIONS FOR CROSSLINKING POLYDIACETYLENE MATERIALS
    IKA, PVS
    FRISCH, HL
    FRISCH, KC
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1985, 23 (04) : 1175 - 1192
12345