Palladium-Catalyzed Carbonylative Esterification of Primary Alcohols with Aryl Chlorides through Dehydroxymethylative C-C Bond Cleavage

被引：27
|
作者：
Park, Hyo-Soon [1 ]
Kim, Dong-Su [1 ]
Jun, Chul-Ho [1 ]
机构：
[1] Yonsei Univ, Dept Chem, Seoul 120749, South Korea
来源：
ACS CATALYSIS | 2015年 / 5卷 / 01期
基金：
新加坡国家研究基金会;
关键词：
C-C activation; carbonylative esterification; catalysis; decarbonylation; palladium; CARBON-CARBON BONDS; COUPLING REACTIONS; METAL INSERTION; HALIDES; FORMATE; HYDROESTERIFICATION; DECARBONYLATION; ACTIVATION; ALDEHYDES; ALKYL;
D O I：
10.1021/cs501778q
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Aryl chlorides in the presence of Pd/C catalyst and NaF react with primary alcohols to form esters, arenes, and alkanes. In this reaction, aryl chlorides act as both oxidants and coupling partners, whereas alcohols serve as both carbonyl sources and alkoxy components of the ester products
引用
收藏
页码：397 / 401
页数：5
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