Complex salts trans-[Rh(β-Pic)4Cl2]X (X = Cl-, ReO 4 - , and ClO 4 - ): Synthesis, crystal structures, and thermal properties

被引：5
|
作者：
Vasil'chenko, D. B. [1 ]
Filatov, E. Yu. [1 ,2 ]
Baidina, I. A. [1 ]
Plyusnin, P. E. [1 ,2 ]
Korenev, S. V. [1 ,2 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2010年 / 36卷 / 05期
关键词：
Clath Rate; Thermolysis; Picoline; Complex Salt; Perrhenate;
D O I：
10.1134/S1070328410050052
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three novel complex salts containing the cation trans-[Rh(beta-Pic)(4)Cl-2](+) with the anions Cl- (I), ReO (4) (-) (II), and ClO (4) (-) (III) were obtained and characterized by elemental analysis, X-ray diffraction, NMR spectroscopy, and IR spectroscopy. The complex trans-[Rh(beta-Pic)(4)Cl-2]ReO4 crystallizes from DMF as a solvate in which solvent molecules fill the channels formed by the cations and anions. The thermal properties of complexes I, II, and II center dot DMF were examined by DTA. Final and some intermediate products of the thermolysis were isolated and characterized by physicochemical methods.
引用
收藏
页码：347 / 352
页数：6
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