Crystal structure of nickel- and cobalt-diazidotetrapyridinemetal(II)-2(pyridine) clathrates

被引：11

作者：

Soldatov, DV

Lipkowski, J

机构：

[1] Russian Acad Sci, Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia

[2] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland

来源：

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY | 1998年 / 30卷 / 02期

关键词：

crystal structure; Werner clathrate; azide; pyridine; Ni(II); Co(II);

D O I：

10.1023/A:1007931115010

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[MPy4(N-3)(2)]. 2Py(M=Ni, Co) are clathrates where two of six pyridine species are included in the crystal structure of the host complex without chemical bonding. The clathrates are isostructural, orthorhombic, space group Pnna(52), Z=4. For the Ni compound a = 14.958(5), b = 11.909(5), c = 17.517(7) Angstrom, V = 3120(2) Angstrom(3), mu = 12.25 cm(-1), final R = 0.057. The Cocompound is of very similar structure (a = 14.980(3), b=11.980(2), c = 17.350(5) Angstrom, V = 3114(1) Angstrom(3), mu = 46.50 cm(-1)). The metal cation in the host molecule is surrounded by six donor nitrogens of two terminal azido-groups in trans-positions and four pyridine ligands. The complex molecule lies on a twofold axis parallel to a.

引用

页码：99 / 109

页数：11

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