Time-resolved infrared absorption spectroscopy of photogenerated electrons in platinized TiO2 particles

被引：185
|
作者：
Yamakata, A [1 ]
Ishibashi, T [1 ]
Onishi, H [1 ]
机构：
[1] Kanagawa Acad Sci & Technol, Surface Chem Lab, Takatsu Ku, Kawasaki, Kanagawa 2130012, Japan
来源：
CHEMICAL PHYSICS LETTERS | 2001年 / 333卷 / 3-4期
关键词：
D O I：
10.1016/S0009-2614(00)01374-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Kinetics of photogenerated electrons in platinized TiO2 (P-25) particles were observed by time-resolved infrared (IR) absorption spectroscopy with AC-coupled detection of cw probe light. The sample irradiated by UV pulse (355 nm and 10 ns) gave transient absorption which monotonously increased in intensity with decreasing wavenumber from 3000 to 900 cm(-1). Photogenerated electrons trapped in shallow mid-gap states were proposed to originate the transient absorption. The decay kinetics of the trapped electrons were fitted to a multi-exponential formula with six lifetimes ranging from 1 x 10(-7) to 3 x 10(-1) s. (C) 2001 Elsevier Science B.V. All rights reserved.
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收藏
页码：271 / 277
页数：7
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