Alcohol addition to acetonitrile activated by the [Re6(μ3-Se)8]2+ cluster core

被引：23
|
作者：
Orto, Peter [1 ]
Selby, Hugh D. [1 ]
Ferris, Daniel [1 ]
Maeyer, Jenine R. [1 ]
Zheng, Zhiping [1 ]
机构：
[1] Univ Arizona, Dept Chem, Tucson, AZ 85721 USA
来源：
INORGANIC CHEMISTRY | 2007年 / 46卷 / 11期
关键词：
D O I：
10.1021/ic7004985
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
d The addition of methanol and ethanol to the previously reported cluster solvates [Re-6(mu(3)-Se)(8)(PEt3)(5)(MeCN)](SbF6)(2) and trans-[Re-6(mu(3)-Se)(8)(PEt3)(4)(CH3CN)(2)][SbF6](2) afforded three cluster complexes with imino ester ligands: {Re-6(mu(3)-Se)(8)(PEt3)(5)[HNC(OCH3)(CH3)]}(SbF6)(2), {Re-6(mu(3)-Se)(8)(PEt3)(5)[HNC(OCH2CH3)(CH3)]}{SbF6}(2), and trans-{Re-6(mu(3)-Se)(8)(PEt3)(4)[HNC(OCH3)(CH3)](2)}{SbF6}(2). In all cases, predominant formation of the Z isomers was observed.
引用
收藏
页码：4377 / 4379
页数：3
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