Bis[μ-1,2-bis(2-pyridyl)ethyne-κ2N:N′]bis[aquadinitratocadmium(II)]

被引：2

作者：

Zaman, MB ^{[1
]}

Davis, MJ ^{[1
]}

Smith, MD ^{[1
]}

zur Loye, HC ^{[1
]}

机构：

[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2003年 / 59卷 / 06期

关键词：

D O I：

10.1107/S0108270103008904

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two twisted 1,2-bis(2-pyridyl) ethyne ligands bridge two Cd2+ centers in the C-2-symmetric title complex, [Cd-2(NO3)(4)(mu-C12H8N2)(2)(H2O)(2)]. The bridging ligands arch across one another creating a 'zigzag loop' molecular geometry. Two nitrate ions and a water molecule complete the irregular seven-coordinate Cd-atom environment. The dihedral angles between the equivalent pyridyl ring planes of the two independent ligands are 67.2 (1)degrees. O-water-H...O-nitrate hydrogen bonding creates two-dimensional layers parallel to the ab plane.

引用

页码：M234 / M236

页数：3

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