The BODIPY-Based Chemosensor for Fluorometric/Colorimetric Dual Channel Detection of RDX and PA

被引:34
|
作者
Gao, Jianmei [1 ,3 ]
Chen, Xiaoxiao [2 ]
Chen, Shuqin [1 ,3 ]
Meng, Hu [1 ]
Wang, Yu [1 ]
Li, Chunsheng [1 ]
Feng, Liang [1 ]
机构
[1] Chinese Acad Sci, Dalian Inst Chem Phys, CAS Key Lab Separat Sci Analyt Chem, Dalian 116023, Peoples R China
[2] Beijing Normal Univ, Coll Chem, Minist Educ, Key Lab Radiopharmaceut, Beijing 100875, Peoples R China
[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
基金
中国国家自然科学基金;
关键词
PICRIC ACID; FLUORESCENT CHEMOSENSORS; QUANTUM DOTS; 2,4,6-TRINITROPHENOL; EXPLOSIVES; NITROAROMATICS; PROBES; SENSOR;
D O I
10.1021/acs.analchem.9b02888
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A fluorometric/colorimetric dual-channel chemosensor based on a hydrazine-substituted BODIPY probe has been successfully fabricated for the detection of RDX and PA. The chemosensor displays turn-on fluorescence behavior upon RDX with a detection limit of 85.8 nM, while showing a turn-off response to PA with a detection limit of 0.44 mu M. Meanwhile, an obvious color difference is observed by the naked-eye after the reaction for RDX. Thus, in application, a two-to-two logic gate is constructed for potential application in explosives detection. Additionally, portable equipment is also developed for in situ determination of RDX.
引用
收藏
页码:13675 / 13680
页数:6
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