Microwave-assisted conversion of D-glucose into lactic acid under solvent-free conditions

被引:47
|
作者
Epane, Geraldine [2 ]
Laguerre, Jean Claude [2 ]
Wadouachi, Anne [1 ]
Marek, Delphine [2 ]
机构
[1] CNRS, UMR 6219, Lab Glucides, F-80039 Amiens, France
[2] Inst Polytech Lasalle Beauvais, F-60026 Beauvais, France
关键词
ALKALINE-DEGRADATION; ORGANIC SYNTHESES; CATALYSTS; CHEMISTRY; GREEN;
D O I
10.1039/b922286c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The microwave-assisted alkaline degradation of D-glucose with alumina supported potassium hydroxide towards its conversion into lactic acid is reported. An experimental design approach was used to optimize the variables involved in this transformation. The reaction succeeded in yielding 75C-% of lactic acid starting from D-glucose using 1.5 equiv of KOH at 180 degrees C. The optimal conditions were applied to D-fructose, D-mannose and D-sucrose.
引用
收藏
页码:502 / 506
页数:5
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