Spreading of completely wetting, non-Newtonian fluids with non-power-law rheology

Spreading non-Newtonian liquids with non-power-law rheology on completely wetting surfaces are seldom investigated. This study assessed the wetting behavior of polydimethylsiloxane (PDMS), a Newtonian fluid, two carboxymethylcellulose (CMC) sodium solutions, a PDMS + 2% w/w silica nanoparticle suspension and three polyethylene glycol (PEG400) + 5-10% w/w silica nanoparticle suspensions (non-power-law fluids) on a mica surface. The 0(D)-U and R-t data for spreading drops of the six tested, non-power-law fluids can be described by power-law wetting models. We propose that this behavior is attributable to a uniform shear rate (a few tens to a few hundreds of s(-1)) distributed over the thin-film regime that controls spreading dynamics. Estimated film thickness was below the resolution of an optical microscope for direct observation. Approximating a general non-Newtonian fluid spreading as a power-law fluid greatly simplifies theoretical analysis and data interpretation. (C) 2010 Elsevier Inc. All rights reserved.