Stabilization of interpenetrating cluster-based frameworks promoted by N-HX hydrogen bonds: synthesis, structures and properties of {[Cd(NH3)4]3[Re3Mo3Se8(CN)6]}X (X = Cl, Br and I)

被引：1
|
作者：
Muravieva, Viktoria K. [1 ,2 ]
Gayfulin, Yakov M. [1 ]
Lemoine, Pierric [2 ]
Naumov, Nikolay G. [1 ,3 ]
Cordier, Stephane [2 ]
机构：
[1] RAS, Nikolaev Inst Inorgan Chem SB, 3 Acad Lavrentiev Ave, Novosibirsk 630090, Russia
[2] Univ Rennes, ISCR, CNRS, UMR 6226, F-35000 Rennes, France
[3] Novosibirsk State Univ, 2 Pirogova Str, Novosibirsk 630090, Russia
来源：
CRYSTENGCOMM | 2018年 / 20卷 / 29期
基金：
俄罗斯基础研究基金会;
关键词：
METAL-ORGANIC FRAMEWORKS; INORGANIC 3D NETWORKS; COORDINATION POLYMERS; CRYSTAL-STRUCTURE; PRUSSIAN BLUE; OCTAHEDRAL RHENIUM; COMPLEXES; ANIONS; CORE; TRANSFORMATION;
D O I：
10.1039/c8ce00527c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Control of covalent coordination polymer structures using non-covalent interactions is a promising way for obtaining functional materials by self-assembly in solution. Here we report the crucial role of halide anions in the formation of interpenetrating frameworks based on cyanometalate clusters. It was found that the interaction of [Re3Mo3Se8(CN)(6)](5-) cluster anions and Cd2+ cations in aqueous ammonia led to the formation of the 1D polymeric compound {[Cd(NH3)(5)](2)[Cd(NH3)(4)](3)[Re3Mo3Se8(CN)(6)](2)}5H(2)O (1). Compound 1 is unstable outside the mother liquor due to the rapid loss of NH3 and H2O molecules. Addition of KX (X = Cl, Br, I) to the reaction mixture led to selective formation of 3D framework compounds {[Cd(NH3)(4)](3)[Re3Mo3Se8(CN)(6)]}X (2-4 for X = Cl, Br, I, respectively) stabilized by N-HX hydrogen bonding. Compounds 2-4 demonstrate high thermal stability as well as reversible loss of ammonia and reversible oxidation in the solid state.
引用
收藏
页码：4164 / 4172
页数：9
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