Preparation and characterization of oxoperoxo tungsten(VI) complexes with morpholinomethyl urea and related ligands

被引:1
|
作者
Pathania, M. S. [1 ]
Sheikh, H. N. [1 ]
Kalsotra, B. L. [1 ]
机构
[1] Univ Jammu, Dept Chem, Jammu 180006, India
关键词
D O I
10.1134/S0036023607020106
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The monooxodiperoxo complexes of tungsten(VI) of the type [WO(O-2)(2) L-L] (where L-L = morpholinomethyl urea, morpholinomethyl thiourea, piperidinomethyl urea, piperidinomethyl thiourea, pyrrolidinomethyl urea, and pyrrolidinomethy thiourea) have been synthesized and characterized by elemental analysis, IR, electronic spectra, magnetic susceptibility, and conductivity measurements, in addition to TGA/DTA. The energy-minimized structures of these complexes have been obtained by molecular modeling using Hyperchem release 7.52.
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页码:197 / 202
页数:6
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