High-field (high-frequency) EPR spectroscopy and structural characterization of a novel manganese(III) corrole

被引：85
|
作者：
Bendix, J
Gray, HB [1 ]
Golubkov, G
Gross, Z
机构：
[1] CALTECH, Beckman Inst, Pasadena, CA 91125 USA
[2] Technion Israel Inst Technol, Dept Chem, IL-32000 Haifa, Israel
[3] Technion Israel Inst Technol, Inst Catalysis Sci & Technol, IL-32000 Haifa, Israel
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 19期
关键词：
D O I：
10.1039/b006299p
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The X-ray structure, magnetic susceptibility, and high-field (high-frequency) EPR spectrum of manganese 5,10,15-tris(pentafluorophenyl) corrole unambiguously establish that the complex contains an isolated, slightly rhombic, manganese(III) center.
引用
收藏
页码：1957 / 1958
页数：2
相关论文
共 50 条
  • [1] High-field and high-frequency EPR
    G. R. Eaton
    S. S. Eaton
    [J]. Applied Magnetic Resonance, 1999, 16 : 161 - 166
  • [2] High-frequency/high-field EPR spectroscopy of metalloproteins and models
    Hagen, WR
    [J]. JOURNAL OF INORGANIC BIOCHEMISTRY, 1999, 74 (1-4) : 28 - 28
  • [3] High-field and high-frequency EPR
    Eaton, GR
    Eaton, SS
    [J]. APPLIED MAGNETIC RESONANCE, 1999, 16 (02) : 161 - 166
  • [4] High-field/High-frequency EPR Spectroscopy in Protein Research: Principles and Examples
    Klaus Möbius
    Anton Savitsky
    [J]. Applied Magnetic Resonance, 2023, 54 : 207 - 287
  • [5] High-field/High-frequency EPR Spectroscopy in Protein Research: Principles and Examples
    Moebius, Klaus
    Savitsky, Anton
    [J]. APPLIED MAGNETIC RESONANCE, 2023, 54 (02) : 207 - 287
  • [6] High-frequency/high-field EPR spectroscopy of the high-spin ferrous ion in hexaaqua complexes
    Telser, J
    van Slageren, J
    Vongtragool, S
    Dressel, M
    Reiff, WM
    Zvyagin, SA
    Ozarowski, A
    Krzystek, J
    [J]. MAGNETIC RESONANCE IN CHEMISTRY, 2005, 43 : S130 - S139
  • [7] EPR spectra from ''EPR-silent'' species: High-field EPR spectroscopy of manganese(III) porphyrins
    Goldberg, DP
    Telser, J
    Krzystek, J
    Montalban, AG
    Brunel, LC
    Barrett, AGM
    Hoffman, BM
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (37) : 8722 - 8723
  • [8] A NOVEL HIGH-FIELD HIGH-FREQUENCY EPR AND ENDOR SPECTROMETER OPERATING AT 3 MM WAVELENGTH
    BURGHAUS, O
    ROHRER, M
    GOTZINGER, T
    PLATO, M
    MOBIUS, K
    [J]. MEASUREMENT SCIENCE AND TECHNOLOGY, 1992, 3 (08) : 765 - 774
  • [9] Pulsed-high Field/High-frequency EPR spectroscopy
    Fuhs, M
    Möbius, K
    [J]. HIGH MAGNETIC FIELDS: APPLICATIONS IN CONDENSED MATTER PHYSICS AND SPECTROSCOPY, 2001, 595 : 476 - 493
  • [10] A high-frequency and high-field EPR study of new azide and fluoride mononuclear Mn(III) complexes
    Mantel, Claire
    Hassan, Alia K.
    Pécaut, Jacques
    Deronzier, Alain
    Collomb, Marie-Noëlle
    Duboc-Toia, Carole
    [J]. J. Am. Chem. Soc., 1600, 40 (12337-12344):
12345