Novel rhodium N-heterocyclic carbene catalysed arylation of aldehydes with phenylboronic acid

被引：19
|
作者：
Yigit, Murat
Ozdemir, Ismail [1 ]
Cetinkaya, Engin
Cetinkaya, Bekir
机构：
[1] Inonu Univ, Fac Sci & Arts, Dept Chem, TR-44280 Malatya, Turkey
[2] Ege Univ, Dept Chem, TR-35100 Bornova, Turkey
来源：
TRANSITION METAL CHEMISTRY | 2007年 / 32卷 / 04期
关键词：
D O I：
10.1007/s11243-007-0208-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of 1,3-dialkylperhydrobenzimidazolinylidene, 1,3-dialkyl-4-methylimidazolinylidene and 1,3-dialkylimidazolinylidene with [RhCl(COD)](2) yields {1,3-dialkylperhydrobenzimidazolin- 2-ylidene}-, {1,3-dialkyl-4-methylimidazolin- 2-ylidene}- {1,3-dialkylimidazolin-2-ylidene} chloro(eta(4)- 1,5- cyclooctadiene) rhodium(I) complexes (2a-c) and ( 4a, b). All compounds synthesised were characterised by elemental analysis, n.m.r. spectroscopy. Phenylboronic acid reacts with aldehydes in the presence of a catalytic amount of the new rhodium(I)-carbene complexes (2a-c) and (4a, b), to give the corresponding aryl secondary alcohols in good yield (73-99%).
引用
收藏
页码：536 / 540
页数：5
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