Charge Interaction between Particle-Laden Fluid Interfaces

Experiments are described where two oil/water interfaces laden with charged particles move at close proximity relative to one another. The particles oil one of the interfaces were observed to be attracted toward the point of closest approach, forming a denser particle monolayer, while the particles oil the opposite interface were repelled away from this point, forming a particle depletion zone. Such particle attraction/repulsion was observed even if one of the interfaces was free of particles. This phenomenon can be explained by the electrostatic interaction between the two interfaces, which causes Surface charges (charged particles and ions) to redistribute in order to Satisfy surface electric equipotential at each interface. In a forced particle oscillation experiment, we demonstrated the control of charged particle positions on the interface by manipulating charge interaction between interfaces.