Partial universality: pinch-off dynamics in fluids with smectic liquid crystalline order

被引:30
|
作者
Savage, John R. [1 ]
Caggioni, Marco [2 ]
Spicer, Patrick T. [2 ]
Cohen, Itai [1 ]
机构
[1] Cornell Univ, Dept Phys, Ithaca, NY 14853 USA
[2] Procter & Gamble Co, Complex Fluid Microstruct, W Chester, OH 45069 USA
关键词
SIMILARITY SOLUTIONS; BREAKUP; RHEOLOGY; THREADS;
D O I
10.1039/b923069f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Droplet pinch-off of fluids with liquid crystalline order is a common yet poorly understood process. We report on measurements of pinch-off dynamics for a lyotropic surfactant/water solution in the lamellar phase and a thermotropic liquid crystal in the smectic phase. We find pinch-off is universal and well described by a similarity solution for a strain thinning power-law fluid. This finding is consistent with bulk rheology measurements which show these materials shear thin with the appropriate power-law dependence. Remarkably, we find depending on material processing, this universal pinch-off cuts off at different length scales. Collectively, these phenomena lead to an exceptional form of singularity where pinch-off is both universal and dependent on initial conditions.
引用
收藏
页码:892 / 895
页数:4
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