Synthesis and characterization of some metal carbonyls with 2-hydroxyacetophenone ethanesulfonylhydrazone

被引：15

作者：

Sentürk, OS ^{[1
]}

Özdemir, Ü

Sert, S

Karacan, N

Ugur, F

机构：

[1] Ege Univ, Fac Sci, Dept Chem, TR-35100 Izmir, Turkey

[2] Gazi Univ, Fac Sci & Literature, Dept Chem, TR-06500 Ankara, Turkey

[3] Natl Res Council Canada, Steacie Inst Mol Sci, Ottawa, ON K1A 0R6, Canada

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 07期

关键词：

photosubstituton; 2-hydroxyacetophenone ethanesulfonylhydrazone; metal carbonyls;

D O I：

10.1016/S1387-7003(03)00152-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Five new complexes, [M(CO)(5)(apesh)] [M = Cr; (1), Mo; (2), W; (3)], [Re(CO)(4) Br(apesh)] (4) and [Mn(CO)(3)(apesh)] (5) have been synthesized by the photochemical reaction of metal carbonyls [M(CO)(6)] (M = Cr, Mo, W), [Re(CO)(5) Br], and [Mn(CO)3 Cp] with 2-hydroxyacetophenone ethanesulfonylhydrazone (apesh). The complexes have been characterized by elemental analysis, mass spectrometry, FT-IR, H-1 NMR spectroscopy. The spectroscopic studies show that apesh behaves as a monodentate ligand coordinating via imine N donor atom in (1)-(4) and as tridentate ligand in (5). (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：926 / 929

页数：4

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