Preparation and characterization of lithium hexafluorophosphate for lithium-ion battery electrolyte

被引：23
|
作者：
Liu Jian-wen [1 ]
Li Xin-hai [1 ]
Wang Zhi-xing [1 ]
Guo Hua-jun [1 ]
Peng Wen-jie [1 ]
Zhang Yun-he [1 ]
Hu Qi-yang [1 ]
机构：
[1] Cent S Univ, Sch Met Sci & Engn, Changsha 410083, Hunan, Peoples R China
来源：
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA | 2010年 / 20卷 / 02期
关键词：
lithium-ion batteries; lithium hexafluorophosphate; phosphorus pentafluoride; acetonitrile;
D O I：
10.1016/S1003-6326(09)60144-8
中图分类号：
TF [冶金工业];
学科分类号：
0806 ;
摘要：
A promising preparation method for lithium hexafluorophosphate (LiPF(6)) was introduced. Phosphorus pentafluoride (PF(5)) was first prepared using CaF(2) and P(2)O(5) at 280 degrees C for 3 h. LiPF(6) was synthesized in acetonitrile solvent by LiF and PF(5) at room temperature (20-30 degrees C) for 4 h. The synthesized LiPF(6) was characterized by infrared spectrometry and X-ray diffraction(XRD). Atomic absorption and ion chromatography results show that the purity of synthesized LiPF(6) reaches 99.98%. Thermal stability of self-synthesized LiPF(6) was analyzed by differential thermal analysis and thermogravimetry. The results indicate that the self-synthesized LiPF(6) has higher purity, lower impurity contents and better thermal stability than the commercial LiPF(6).
引用
收藏
页码：344 / 348
页数：5
相关论文
共 50 条
  • [1] Preparation and characterization of lithium hexafluorophosphate for lithium-ion battery electrolyte
    刘建文
    李新海
    王志兴
    郭华军
    彭文杰
    张云河
    胡启阳
    [J]. Transactions of Nonferrous Metals Society of China, 2010, 20 (02) : 344 - 348
  • [2] Preparation of polymer electrolyte for lithium-ion battery
    Ren, XM
    Gu, H
    Chen, LQ
    Wu, F
    Huang, XFJ
    [J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2002, 23 (07): : 1383 - 1385
  • [3] LiBF4 Electrolyte for Lithium-Ion Battery: Preparation and Characterization
    Liu Jian-Wen
    Li Xin-Hai
    Wang Zhi-Xing
    Guo Hua-Jun
    Hu Qi-Yang
    [J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2009, 25 (01) : 31 - 36
  • [4] Synthesis and characterization of LiBOB as electrolyte for lithium-ion battery
    Wigayati, Etty Marti
    Lestariningsih, Titik
    Subhan, Achmad
    Ratri, Christin Rina
    Purawiardi, Ibrahim
    [J]. IONICS, 2016, 22 (01) : 43 - 50
  • [5] Synthesis and characterization of LiBOB as electrolyte for lithium-ion battery
    Etty Marti Wigayati
    Titik Lestariningsih
    Achmad Subhan
    Christin Rina Ratri
    Ibrahim Purawiardi
    [J]. Ionics, 2016, 22 : 43 - 50
  • [6] Lithium salts of heteropolyacid as the electrolyte of lithium-ion battery
    Chen, YG
    Wang, CG
    Zhang, XY
    Xie, DM
    Wang, RS
    [J]. SYNTHETIC METALS, 2003, 135 (1-3) : 225 - 226
  • [7] Investigation of Lithium Tetrafluorooxalatophosphate as a Lithium-Ion Battery Electrolyte
    Xu, Mengqing
    Xiao, Ang
    Li, Weishan
    Lucht, Brett L.
    [J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 2009, 12 (08) : A155 - A158
  • [8] Is it worthwhile to recover lithium-ion battery electrolyte during lithium-ion battery recycling?
    Vanderburgt, Stephen
    Santos, Rafael M.
    Chiang, Yi Wai
    [J]. RESOURCES CONSERVATION AND RECYCLING, 2023, 189
  • [9] Preparation and characterization of a novel kind of polymer electrolyte composite membrane for lithium-ion on battery
    Feng Hua-Jun
    Chen Yuan
    Dai Ke-Hua
    Song Zhao-Shuang
    Ma Jian-Wei
    Qi Lu
    [J]. ACTA PHYSICO-CHIMICA SINICA, 2007, 23 (12) : 1922 - 1926
  • [10] Preparation and characterization of nanofibrous cellulose as solid polymer electrolyte for lithium-ion battery applications
    Sabrina, Qolby
    Ratri, Christin Rina
    Hardiansyah, Andri
    Lestariningsih, Titik
    Subhan, Achmad
    Rifai, Abdulloh
    Yudianti, Rike
    Uyama, Hiroshi
    [J]. RSC ADVANCES, 2021, 11 (37) : 22929 - 22936
12345