Aerobic ruthenium-catalyzed oxidative transformation of secondary amines to imines

被引：119
|
作者：
Murahashi, Shun-Ichi [1 ]
Okano, Yuriko
Sato, Hideomi
Nakae, Takahiro
Komiya, Naruyoshi
机构：
[1] Osaka Univ, Grad Sch Engn Sci, Dept Chem, 1-3 Machikaneyama, Osaka 5608531, Japan
[2] Okayama Univ Sci, Fac Engn, Dept Appl Chem, Okayama 7000005, Japan
来源：
SYNLETT | 2007年 / 11期
关键词：
ruthenium; oxidations; molecular oxygen; amines; imines;
D O I：
10.1055/s-2007-984515
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Aerobic, catalytic oxidation of secondary amines is performed efficiently in the presence of a diruthenium complex catalyst Ru-2(OAc)(4)Cl to give the corresponding imines. The catalytic system is characterized by its high selectivity, activity, and operational simplicity.
引用
收藏
页码：1675 / 1678
页数：4
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