Suzuki-Miyaura Cross-Coupling Reactions in Aqueous Media: Green and Sustainable Syntheses of Biaryls

被引：333

作者：

Polshettiwar, Vivek ^{[1
]}

Decottignies, Audrey ^{[2
]}

Len, Christophe ^{[2
]}

Fihri, Aziz ^{[2
]}

机构：

[1] King Abdullah Univ Sci & Technol, KCC, Thuwal 23955, Saudi Arabia

[2] ESCOM UTC, F-60200 Compiegne, France

来源：

CHEMSUSCHEM | 2010年 / 3卷 / 05期

关键词：

cross coupling; green chemistry; microwave chemistry; palladium; sustainable chemistry; water chemistry; RING-CLOSING METATHESIS; ARYL CHLORIDES; ROOM-TEMPERATURE; ARYLBORONIC ACIDS; PALLADIUM-COMPLEX; PHENYLBORONIC ACID; AEROBIC CONDITIONS; MESOPOROUS SILICA; UNPROTECTED HALONUCLEOSIDES; CARBAPALLADACYCLE COMPLEX;

D O I：

10.1002/cssc.200900221

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbon-carbon cross-coupling reactions are among the most important processes in organic chemistry, and Suzuki-Miyaura reactions are among the most widely used protocols for the formation of carbon-carbon bonds. These reactions are generally catalyzed by soluble palladium complexes with various ligands. However, the use of toxic organic solvents remains a scientific Challenge and an aspect of economical and ecological relevance. This-Review will summarize various recently developed significant methods by which the Suzuki-Miyaura coupling was conducted in aqueous media, and analyzes if they are "real green" protocols.

引用

页码：502 / 522

页数：21

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