Cu-Ni Bimetallic Hydroxide Catalyst for Efficient Electrochemical Conversion of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid

被引：54
|
作者：
Chen, Hao [1 ,2 ]
Wang, Jiatuan [1 ]
Yao, Yuan [3 ]
Zhang, Zihao [1 ]
Yang, Zhenzhen [4 ]
Li, Jing [1 ]
Chen, Kequan [5 ]
Lu, Xiuyang [1 ]
Ouyang, Pingkai [1 ,5 ]
Fu, Jie [1 ,2 ]
机构：
[1] Zhejiang Univ, Coll Chem & Biol Engn, Key Lab Biomass Chem Engn, Minist Educ, Hangzhou 310027, Zhejiang, Peoples R China
[2] Inst Zhejiang Univ Quzhou, 78 Jiuhua Blvd North, Quzhou 324000, Peoples R China
[3] Shanghai Normal Univ, Coll Chem & Mat Sci, Shanghai 200234, Peoples R China
[4] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA
[5] Nanjing Tech Univ, Coll Biotechnol & Pharmaceut Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 211816, Jiangsu, Peoples R China
来源：
CHEMELECTROCHEM | 2019年 / 6卷 / 23期
基金：
中国国家自然科学基金;
关键词：
electrochemical conversion; 5-hydroxymethylfurfural; 2; 5-furandicarboxylic acid; catalysis; FREE AEROBIC OXIDATION; HYDROGEN-PRODUCTION; SUPPORTED AU; BIOMASS; WATER; NICKEL; FUELS; OXIDE;
D O I：
10.1002/celc.201901366
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
2,5-furandicarboxylic acid (2,5-FDCA) produced from 5-hydroxymethylfurfural (5-HMF) is a promising renewable alternative to terephthalic acid. In this work, we prepared a Cu-Ni bimetallic catalyst with a CuNi(OH)(2) structure by incipient wetness impregnation. This catalyst gave a 9.2 mA cm(-2) current density for 5-HMF oxidation at 1.45 V vs RHE. Finally, 100 % conversion of HMF with 93.3 % yield of 2,5-FDCA was obtained.
引用
收藏
页码：5797 / 5801
页数：5
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