Synthesis of "V-shaped" syn-bidentate ligands based on mesitylene-derived [1.1.1.1]metacyclophane blocked in a 1,3-alternate conformation

被引：10
|
作者：
Klein, C [1 ]
Graf, E
Hosseini, MW
De Cian, A
Kyritsakas-Gruber, N
机构：
[1] Univ Strasbourg, Chim Coordinat Organ Lab, F-67000 Strasbourg, France
[2] Univ Strasbourg, Federat Rech Chim, Serv Commun Rayons X, F-67000 Strasbourg, France
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 2003卷 / 02期
关键词：
cyclophanes; pyridines; nitriles; ligands; thioethers;
D O I：
10.1002/ejoc.200390046
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of five new syn-bidentate ligands 14-18 based on the [1.1.1.1]metacyclophane backbone blocked in a 1,3-alternate conformation was achieved. The common building block for the preparation of ligands bearing two interaction sites located in a syn fashion (CN, SMe, p-pyridyl, p-methoxyphenyl and p-methylthiophenyl) is the dibromo derivative 12. All reported ligands were fully characterised by classical analytical methods and their 1,3-alternate conformation demonstrated. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).
引用
收藏
页码：395 / 399
页数：5
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