The improved Kolbe-Schmitt reaction using supercritical carbon dioxide

被引：21
|
作者：
Iijima, Takayuki [1 ]
Yamaguchi, Tatsuaki [1 ]
机构：
[1] Chiba Inst Technol, Fac Engn, Dept Life & Environm Sci, Narashino, Chiba 2750016, Japan
来源：
TETRAHEDRON LETTERS | 2007年 / 48卷 / 30期
关键词：
supercritical carbon dioxide; sodium phenoxide; salicylic acid; p-hydroxybenzoic acid; Kolbe-Schmitt reaction;
D O I：
10.1016/j.tetlet.2007.05.132
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A comparative analysis of the reactions between sodium phenoxide and CO2 under the gaseous and supercritical conditions has demonstrated the preferential effect of supercritical conditions for promoting the reactivity Of CO2. A significant increase in product yield was obtained in supercritical CO2 compared to reactions undertaken in gaseous CO2. (C) 2007 Elsevier Ltd. All rights reserved.
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页码：5309 / 5311
页数：3
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