Transesterification of (hetero)aryl esters with phenols by an Earth-abundant metal catalyst

被引：11

作者：

Chen, Jianxia ^{[1
]}

Namila, E. ^{[1
]}

Bai, Chaolumen ^{[1
]}

Baiyin, Menghe ^{[1
]}

Agula, Bao ^{[1
]}

Bao, Yong-Sheng ^{[1
]}

机构：

[1] Inner Mongolia Normal Univ, Coll Chem & Environm Sci, Inner Mongolia Key Lab Green Catalysis, Hohhot 010022, Peoples R China

来源：

RSC ADVANCES | 2018年 / 8卷 / 44期

基金：

美国国家科学基金会;

关键词：

CROSS-COUPLING REACTIONS; N-HETEROCYCLIC CARBENES; C-O; AROMATIC HETEROCYCLES; ARYL ESTERS; NICKEL; SILYLATION; ALCOHOLS; AZOLES; DERIVATIVES;

D O I：

10.1039/c8ra04984j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Readily available and inexpensive Earth-abundant alkali metal species are used as efficient catalysts for the transesterification of aryl or heteroaryl esters with phenols which is a challenging and underdeveloped transformation. The simple conditions and the use of heterogeneous alkali metal catalyst make this protocol very environmentally friendly and practical. This reaction fills in the missing part in transesterification reaction of phenols and provides an efficient approach to aryl esters, which are widely used in the synthetic and pharmaceutical industry.

引用

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页码：25168 / 25176

页数：9

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