Study of cyclic borinates obtained from piperidine- and piperazine alcohols by spectroscopic methods and X-ray crystallography

被引：25
|
作者：
Hopfl, H
Farfan, N
Castillo, D
Santillan, R
Gutierrez, A
Daran, JC
机构：
[1] Univ Autonoma Estado Morelos, Ctr Invest Quim, Cuernavaca 62210, Morelos, Mexico
[2] Inst Politecn Nacl, Ctr Invest & Estudios Avanzados, Dept Quim, Mexico City 07000, DF, Mexico
[3] Univ Autonoma Metropolitana Ixtapalapa, Unidad Ixtapalapa, Lab Resonancia Magnet Nucl, Ixtapalapa 09340, Mexico
[4] CNRS, Chim Coordinat Lab, F-31077 Toulouse, France
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 553卷 / 1-2期
关键词：
borinates; boron complexes; piperidine- and piperazine alcohols; coordinative N -> B bond; X-ray crystallography;
D O I：
10.1016/S0022-328X(97)00636-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of eleven new 2-aminoethyl- and 3-aminopropyl borinate derivatives with a coordinative N --> B bond has been synthesized by condensation reactions between piperidine-as well as piperazine alcohols and diphenylborinic acid. The products obtained are analogous to N-spiro compounds and bicyclic systems and have been characterized by spectroscopic methods and X-ray crystallography. Thereby the N --> B bond and the geometry of this new heterocyclic systems have been studied in more detail. (C) 1998 Elsevier Science S.A.
引用
收藏
页码：221 / 239
页数：19
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