Crystal growth and vibrational spectroscopic studies of the semiorganic non-linear optical crystal - bisthiourea zinc chloride

被引:81
|
作者
Krishnakumar, V [1 ]
Nagalakshmi, R [1 ]
机构
[1] Nehru Mem Coll, Dept Phys, Tiruchirappalli 621007, India
关键词
bisthiourea zinc chloride; infrared; polarized Raman; optical transmission; second harmonic generation;
D O I
10.1016/j.saa.2004.04.014
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
The semiorganic non-linear optical crystal bisthiourea zinc chloride (BTZQ) was grown by mixed solvent slow evaporation technique. The solubilities under various solvents in different proportions have been studied. Vibrational spectra were recorded to determine the symmetries of molecular vibrations. The observed Raman and infrared bands were also assigned and discussed. The optical transmission spectral study was also carried out. The property of second harmonic generation of BTZC was also verified. (C) 2004 Elsevier B.V. All rights reserved.
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页码:499 / 507
页数:9
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