Copper-catalyzed regioselective allylic substitution reactions with indium organometallics

被引：42

作者：

Rodríguez, D ^{[1
]}

Sestelo, JP ^{[1
]}

Sarandeses, LA ^{[1
]}

机构：

[1] Univ A Coruna, Dept Quim Fundamental, E-15071 La Coruna, Spain

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 68卷 / 06期

关键词：

D O I：

10.1021/jo0265939

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first nucleophilic allylic substitution reactions of triorganoindium compounds with allylic halides and phosphates are reported. The reactions of trialkyl- and triarylindium reagents with cinnamyl and geranyl halides and phosphates, with the aid of copper catalysis [Cu(OTf)(2)/ P(OEt)(3)], are described. In general, the reaction proceeds efficiently to give good yields and regioselectively to afford the S(N)2' product.

引用

页码：2518 / 2520

页数：3

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