Synthesis of Dibromo[3.3]paracyclophanes

被引：3

作者：

Shibahara, Masahiko ^{[1
]}

Watanabe, Motonori ^{[2
]}

Miyazaki, Takaaki ^{[3
,4
]}

Goto, Kenta ^{[4
]}

Shinmyozu, Teruo ^{[5
]}

机构：

[1] Oita Univ, Fac Educ & Welf Sci, Dept Chem, 700 Dannoharu, Oita 8701192, Japan

[2] Kyushu Univ, Int Inst Carbon Neutral Energy Res I2CNER, Nishi Ku, 744 Motooka, Fukuoka 8190395, Japan

[3] Acad Sinica, Inst Chem, 128,Acad Rd Sec 2, Taipei 11529, Taiwan

[4] Kyushu Univ, IMCE, Nishi Ku, 744 Motooka, Fukuoka 8190395, Japan

[5] Natl Taiwan Univ, Dept Chem, 1,Sec 4,Roosevelt Rd, Taipei 10617, Taiwan

来源：

SYNTHESIS-STUTTGART | 2016年 / 48卷 / 08期

基金：

日本学术振兴会;

关键词：

cyclophanes; NMR; X-ray crystal structure; coupling reaction; Wolff-Kishner reduction; PI-PI-INTERACTION; MACRO RINGS; THROUGH-SPACE; PHOTOPHYSICAL PROPERTIES; CONJUGATED POLYMERS;

D O I：

10.1055/s-0035-1560421

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

All possible pseudogeminal-, pseudoortho-, pseudometa-, and pseudopara-dibromo[3.3] paracyclophanes were synthesized by the (p-tolylsulfonyl) methyl isocyanide (TosMIC) coupling method, and characterized by the aromatic proton signals of the H-1 NMR spectra and finally by the X-ray crystal structure analyses of the pseudogeminal, pseudoortho, and pseudopara isomers.

引用

页码：1197 / 1201

页数：5

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