Third-order nonlinear optical properties of sulfide glasses -: La2S3-Ga2S3 binary and MS-La2S3-Ga2S3 (MS = PbS, Ag2S and Na2S) ternary glasses

被引：4
|
作者：
Zhou, ZH [1 ]
Nasu, H [1 ]
Hashimoto, T [1 ]
Kamiya, K [1 ]
机构：
[1] Mie Univ, Fac Engn, Dept Chem Mat, Tsu, Mie 514, Japan
来源：
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN | 1997年 / 105卷 / 12期
关键词：
third-order nonlinear optical susceptibility; third harmonic generation method; sulfide glasses;
D O I：
10.2109/jcersj.105.1079
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
The dependence of the third-order nonlinear optical properties of the La2S3-Ga2S3 and MS-La2S3-Ga2S3 (MS = PbS, Ag2S and Na2S) glasses on the composition, linear refractive index and optical band gap was examined. The chi((3)), Of the glasses was similar to 10(-12) esu, which was about 100 times as large as that of silica glass, and was increased with the increase of La2S3 content in the La2S3-Ga2S3 binary glasses, while it was increased with the substitution of PbS or Ag2S for La2S3 and decreased when La2S3 was replaced by Na2S. The chi((3)) of the glasses was found to increase with the increase of linear refractive index and the decrease of band gap, being in accordance with the empirical Miller's rule and optical band gap model.
引用
收藏
页码：1079 / 1085
页数：7
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