Ba4[Mn3N6], a Quasi-One-Dimensional Mixed-Valent Nitridomanganate (II, IV)

被引：6
|
作者：
Ovchinnikov, Alexander [1 ,2 ]
Bobnar, Matej [1 ]
Prots, Yurii [1 ]
Schnelle, Walter [1 ]
Hoehn, Peter [1 ]
Grin, Yuri [1 ]
机构：
[1] Max Planck Inst Chem Phys Fester Stoffe, Nothnitzer Str 40, D-01187 Dresden 40, Germany
[2] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA
来源：
CRYSTALS | 2018年 / 8卷 / 06期
关键词：
nitridometalate; crystal structure; powder diffraction; magnetism; SINGLE-CRYSTAL GROWTH; QUATERNARY NITRIDE; CHAINS;
D O I：
10.3390/cryst8060235
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The mixed-valent nitridomanganate Ba-4[Mn3N6] was prepared using a gas-solid high temperature route. The crystal structure was determined employing high resolution synchrotron powder diffraction data: space group Pbcn, a = 9.9930(1) angstrom, b = 6.17126(8) angstrom, c = 14.4692(2) angstrom, V = 892.31(2) angstrom(3), Z = 4. The manganese atoms in the structure of Ba-4[Mn3N6] are four-fold coordinated by nitrogen forming infinite corrugated chains of edge-sharing [MnN4] tetrahedra. The chains demonstrate a complete charge order of Mn species. Magnetization measurements and first principle calculations indicate quasi-one dimensional magnetic behavior. In addition, chemical bonding analysis revealed pronounced Mn-Mn interactions along the chains.
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页数：14
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