Effect of SEI Component on Graphite Electrode Performance for Li-Ion Battery Using Ionic Liquid Electrolyte

被引:23
|
作者
Nakatani, Naoki [1 ]
Kishida, Kazuhisa [1 ]
Nakagawa, Kiyoharu [1 ]
机构
[1] Kansai Univ, Dept Chem, Energy & Environm Engn & High Technol Res Core HR, Suita, Osaka 5648680, Japan
关键词
LITHIUM-ION; PROPYLENE CARBONATE; ANODE; BIS(TRIFLUOROMETHYLSULFONYL)AMIDE; BIS(FLUOROSULFONYL)IMIDE; INTERCALATION; ADDITIVES;
D O I
10.1149/2.0361809jes
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
In this study, we investigated the role of solid electrolyte interface (SET) films in the cells fabricated with the ionic liquids ([N-2,N-2,N-1(201)][TFSI] and [Li(G4)][TFSI]). The SET was introduced beforehand to the graphite electrode, which facilitated the intercalation of Li-ions into the graphite electrode in [Li(G4)][TFSI]. In addition, the discharge capacity in the case of the cell fabricated with [Li(G4)][TFSI] was almost similar to that observed in the case of the cell fabricated with organic electrolyte. The SET performed the pulling apart combination of glyme and Li-ion. Identification analysis of the SET component having action of extracting Li-ion from [Li(G4)] was carried out. (C) The Author(s) 2018. Published by ECS.
引用
收藏
页码:A1621 / A1625
页数:5
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