Dielectric and optical studies of phase transitions in [(CH3)2NH2]5Cd2CuCl11 crystal

被引:1
|
作者
Elyashevskyy, Y
Dacko, S
Kosturek, B
Czapla, Z
Kapustyanik, VB
机构
[1] Univ Wroclaw, Inst Expt Phys, PL-50204 Wroclaw, Poland
[2] Lvov Ivan Franko State Univ, UA-79017 Lvov, Ukraine
来源
关键词
D O I
10.1002/pssb.200409056
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Single crystals of [(CH3)(2) NH2](5)Cd2CuCl11 have been grown and their dielectric and optical properties have been studied. Electric permittivity, losses and linear optic birefringence measurements have shown that the obtained new crystal is isomorphous with the original one - [(CH3)(2) NH2](5)Cd3C11. Phase transitions were observed at 175 K (continuous) and 120 K (first order). It means that partial replacing of cadmium atoms by copper ones does not change the structure and the heavy Cd2CuCl11-2 anions do not influence significantly the interaction of dimethylammonium cations. (C) 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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页码:R57 / R59
页数:3
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