Low-temperature fabrication of steatite ceramics with boron oxide addition
被引:21
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作者:
Soykan, H. S.
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Eregli Iron & Steel Works Co, Dept Res & Technol Dev, TR-67300 Zonguldak, TurkeyEregli Iron & Steel Works Co, Dept Res & Technol Dev, TR-67300 Zonguldak, Turkey
Soykan, H. S.
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机构:
[1] Eregli Iron & Steel Works Co, Dept Res & Technol Dev, TR-67300 Zonguldak, Turkey
Steatite ceramics have been fabricated by using coarse starting materials such as talc, clay, and barium carbonate with addition of boron oxide (B2O3). B2O3 has been found to be a useful flux to densify MgO-Al2O3-SiO2-BaO (MASB) powders. The steatite ceramic with a relative density of 97% was obtained at a sintering temperature of 1200 degrees C. The temperatures needed to densify MASB powders decrease with increase of B2O3 addition. For the same sintering temperature, as the amount of B2O3 addition increases, the crystallization rate of protoenstatite increase. Large pores and visible cracks were seen in B2O3-free samples, while pore elimination and enhancement of densification for B2O3-added steatites were promoted by the viscous flow due to B2O3. Hence, nearly dense ceramics were obtained for use in high temperature electrical applications. (C) 2006 Elsevier Ltd and Techna Group S.r.l. All rights reserved.