Solid state organic amine detection in a photochromic porous metal organic framework

被引：335
|
作者：
Mallick, Arijit [1 ,2 ]
Garai, Bikash [1 ,2 ]
Addicoat, Matthew A. [3 ]
Petkov, Petko St. [3 ]
Heine, Thomas [3 ]
Banerjee, Rahul [1 ,2 ]
机构：
[1] Natl Chem Lab, CSIR, Phys Mat Chem Div, Pune 411008, Maharashtra, India
[2] Acad Sci & Innovat Res AcSIR, New Delhi, India
[3] Jacobs Univ Bremen, Sch Sci & Engn, D-28759 Bremen, Germany
来源：
CHEMICAL SCIENCE | 2015年 / 6卷 / 02期
关键词：
COORDINATION POLYMERS; CHEMICAL SENSORS; ENCAPSULATION;
D O I：
10.1039/c4sc03224a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new Mg(II) based photochromic porous metal-organic framework (MOF) has been synthesized bearing naphthalenediimide (NDI) chromophoric unit. This MOF (Mg-NDI) shows instant and reversible solvatochromic behavior in presence of solvents with different polarity. Mg-NDI also exhibits fast and reversible photochromism via radical formation. Due to the presence of electron deficient NDI moiety, this MOF exhibits selective organic amine (electron rich) sensing in solid state. The organic amine detection has been confirmed by photoluminescence quenching experiment and visual color change.
引用
收藏
页码：1420 / 1425
页数：6
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