Cyclization of 3-cyclopent-2-enyl-4-hydroxy[1]benzopyran-2-one

被引:2
|
作者
Majumdar, KC [1 ]
Biswas, P [1 ]
Choudhury, PK [1 ]
机构
[1] Univ Kalyani, Dept Chem, Kalyani 741235, W Bengal, India
关键词
D O I
10.1080/00397910008087020
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Cyclization of 3-cyclopent-2-enyl-4-hydroxy[1]benzopyran-2-one (1) with cold cone. sulfuric acid gave a mixture of two products, 2 (10%) and 3 (80%). However, on treatment with mercuric chloride 1 furnished the linear product 4 in 60% yield while with mercuric acetate the bicyclic product 8 was obtained in 50% yield. The structures of products are established by chemical correlation.
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页码:4047 / 4056
页数:10
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