Exfoliation of α-hydroxides of nickel and cobalt in water

被引：35

作者：

Nethravathi, C. ^{[1
]}

Viswanath, B. ^{[2
]}

Sebastian, Mency ^{[1
]}

Rajamathi, Michael ^{[1
]}

机构：

[1] St Josephs Coll, Dept Chem, Mat Res Grp, Bangalore 560027, Karnataka, India

[2] Indian Inst Sci, Mat Res Ctr, Bangalore 560012, Karnataka, India

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2010年 / 345卷 / 01期

关键词：

alpha-Hydroxides of nickel/cobalt; Intercalation; Exfoliation; LAYERED DOUBLE HYDROXIDES; POSITIVELY CHARGED NANOSHEETS; GRAPHITE OXIDE; SOLVOTHERMAL DECOMPOSITION; COLLOIDAL DISPERSIONS; DODECYL-SULFATE; ANIONIC CLAY; THIN-FILMS; DELAMINATION; BEHAVIOR;

D O I：

10.1016/j.jcis.2010.01.047

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

p-Aminobenzoate ion intercalated alpha-hydroxides of nickel/cobalt were synthesized by precipitation using ammonia (pH = similar to 12). Aqueous colloidal suspension of alpha-hydroxide of nickel/cobalt was obtained on washing the precipitate as the pH was reduced to similar to 7. The development of partial positive charge on the amine end of the intercalated anion causes repulsion between the layers leading to exfoliation and colloidal suspension of monolayers in water. While the layers could be restacked from the colloidal suspension in the presence of other anions in the case of alpha-cobalt hydroxide, the exfoliation could not be reversed easily in the case of the nickel analog. (C) 2010 Elsevier Inc. All rights reserved.

引用

页码：109 / 115

页数：7

共 50 条

[1] GASEOUS HYDROXIDES OF COBALT AND NICKEL
BELTON, GR
JORDAN, AS
JOURNAL OF PHYSICAL CHEMISTRY, 1967, 71 (12): : 4114 - &
[2] SPECIFIC CHARACTER OF NICKEL AND COBALT ABSORPTION FROM SEA-WATER BY NATURAL IRON HYDROXIDES AND MANGANESE HYDROXIDES
PRONINA, NV
VARENTSO.IM
DOKLADY AKADEMII NAUK SSSR, 1973, 210 (04): : 944 - 947
[3] CATHODICALLY DEPOSITED NICKEL-(II)-HYDROXIDES AND COBALT (II)-HYDROXIDES
BODE, H
DEHMELT, K
WITTE, J
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1963, 110 (03) : C69 - C69
[4] Interaction of κ-carrageenan with nickel, cobalt, and iron hydroxides
Jones, F
Cölfen, H
Antonietti, M
BIOMACROMOLECULES, 2000, 1 (04) : 556 - 563
[5] MIXED BASIC NITRATES AND MIXED HYDROXIDES OF NICKEL AND COBALT
MANNOORETTONNIL, M
GILBERT, J
BULLETIN DES SOCIETES CHIMIQUES BELGES, 1973, 82 (5-6): : 383 - 395
[6] Interstratified hybrids of α-hydroxides of nickel and cobalt as supercapacitor electrode materials
Sebastian, Mency
Nethravathi, C.
Rajamathi, Michael
MATERIALS RESEARCH BULLETIN, 2013, 48 (07) : 2715 - 2719
[7] Synthesis and spectroscopic identification of nickel and cobalt layered hydroxides and hydroxynitrates
Wallbridge, Samuel P.
Lawson, Kurt
Catling, Amy E.
Kirk, Caroline A.
Dann, Sandra E.
DALTON TRANSACTIONS, 2022, 51 (47) : 18010 - 18023
[8] Electrochemical Exfoliation and Growth of Nickel-Cobalt Layered Double Hydroxides@Black Phosphorus Hetero-Nanostructure Textiles for Robust Foldable Supercapacitors
Zheng, Yun
Zhang, Yang
Man, Zengming
Chen, Wenxing
Lu, Wangyang
Wu, Guan
ADVANCED FUNCTIONAL MATERIALS, 2024, 34 (39)
[9] STUDY OF SORPTION OF NICKEL AND COBALT (BIOGENIC FORMS) FROM SEA-WATER BY NATURAL IRON AND MANGANESE HYDROXIDES
PRONINA, NV
VARENTSO.IM
SPEKTORO.LV
SPEKTORO.KS
OVSYANNI.MN
GEOKHIMIYA, 1973, (06): : 876 - 886
[10] Nanostructured particles by controlled precipitation techniques -: Example of nickel and cobalt hydroxides
Coudun, Corinne
Amblard, Etienne
Guihaume, Julie
Hochepied, Jean-Francois
CATALYSIS TODAY, 2007, 124 (1-2) : 49 - 54

← 1 2 3 4 5 →