Studies on the asymmetric synthesis of (R)-α-terpineol

被引：0

作者：

Pei, W ^{[1
]}

机构：

[1] Yanbian Univ, Dept Chem, Yanji 133002, Peoples R China

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 1998年 / 19卷 / 03期

关键词：

asymmetric catalysis; terpineol; synthesis;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(R)-alpha-Terpineol, a natural product, was synthesized enantioselectively by an asymmetric catalyzed Diels-Alder reaction from 1-phenylsulfonyl-3-buten-8-one with 2-methyl-1,3-butadiene. The optical purity of (R)-alpha-terpineol was obtained in 92% ee.

引用

页码：399 / 401

页数：3

共 5 条

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[4] Exclusively endo-selective Lewis acid-catalyzed hetero Diels-Alder reactions of (E)-1-phenylsulfonyl-3-alken-2-ones with vinyl ethers
Wada, E
Pei, W
Yasuoka, H
Chin, U
Kanemasa, S
[J]. TETRAHEDRON, 1996, 52 (04) : 1205 - 1220
[5] WADE E, 1994, CHEM LETT, P2345

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