Pd(0)-catalyzed amphiphilic allylation of aldehydes with vinyl epoxide

被引：29
|
作者：
Kimura, Masanari [1 ]
Mukai, Ryutaro [1 ]
Tamaki, Takato [1 ]
Horino, Yoshikazu [1 ]
Tamaru, Yoshinao [1 ]
机构：
[1] Nagasaki Univ, Fac Engn, Dept Appl Chem, Nagasaki 8528521, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 14期
关键词：
D O I：
10.1021/ja0687320
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Under Pd(0)-Et3B catalysis, vinyl epoxide serves as a formal 3-butenyl 2-anion-1-cation equivalent, and the cation reacts with aldehydes at the alpha-position, and the anion, at the carbonyl carbon, furnishing 2-vinylcyclobutanols in one pot.
引用
收藏
页码：4122 / +
页数：3
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