Perovskite La0.6Sr0.4Co0.2Fe0.8O3 Nanofibers Decorated with RuO2 Nanoparticles as an Efficient Bifunctional Cathode for Rechargeable Li-O2 Batteries

被引:26
|
作者
Gong, Yudong [1 ]
Zhang, Xiuling [2 ]
Li, Zhipeng [2 ]
Wang, Zhiwei [2 ,3 ]
Sun, Chunwen [1 ,2 ,3 ]
Chen, Liquan [1 ]
机构
[1] Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Beijing Inst Nanoenergy & Nanosyst, Beijing 100083, Peoples R China
[3] Natl Ctr Nanosci & Technol NCNST, CAS Ctr Excellence Nanosci, Beijing 100190, Peoples R China
来源
CHEMNANOMAT | 2017年 / 3卷 / 07期
基金
美国国家科学基金会;
关键词
cycle stability; electrospinning; Li-air batteries; perovskites; ruthenium oxide; LITHIUM-AIR BATTERIES; OXYGEN REDUCTION REACTION; BINDER-FREE; RUTHENIUM NANOPARTICLES; CATALYST; ELECTROCATALYST; CARBON; PERFORMANCE; COMPOSITE; LIFE;
D O I
10.1002/cnma.201700071
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Perovskite La0.6Sr0.4Co0.2Fe0.8O3 nanofibers decorated with RuO2 nanoparticles (RuO2@LSCF-NFs) are prepared by electrospinning combined with a facile synthesis method. The obtained RuO2@LSCF-NFs are used as a cathode catalyst for lithium-oxygen (Li-O-2) batteries. The RuO2@LSCF-NFs catalyst exhibits enhanced catalytic performance with a decreasing voltage gap of 283mV lower than the cell with the LSCF-NFs catalyst. The improved performance is attributed to the superior catalytic activation of RuO2 nanoparticles toward oxygen evolution reaction (OER).
引用
收藏
页码:485 / 490
页数:6
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