Catalytic oxidation of iron(II) aqua complex by oxygen in the presence of palladium(II) tetraaqua complex

被引：0

作者：

Potekhin, VV ^{[1
]}

Solov'eva, SN ^{[1
]}

Potekhin, VM ^{[1
]}

机构：

[1] St Petersburg State Inst Technol, St Petersburg, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2004年 / 74卷 / 05期

关键词：

D O I：

10.1023/B:RUGC.0000039070.98591.c1

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The catalytic oxidation of iron(II) with oxygen occurs along with an autocatalytic reaction between palladium(II) tetraaqua complex and iron(II) aqua complex in an oxygen atmosphere. The reaction is catalyzed by a compound of palladium in an intermediate oxidation state, presumably by a small palladium cluster formed in the course of the reduction of palladium(II) tetraaqua complex with iron(II) aqua complex.

引用

页码：647 / 650

页数：4

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