Synthesis and X-ray characterization of the new hydrogen-bonded framework [Cu(2,2′-bipy){OP(CH2PO3H2)(CH2PO3H)2}]n

被引:12
|
作者
Midollini, S
Orlandini, A
Vacca, A
机构
[1] CNR, Ist Chim Composti Organometallici, I-50019 Florence, Italy
[2] Univ Florence, Dipartimento Chim, I-50019 Florence, Italy
关键词
copper(II) complex; H-bonded network; tripodal phosphonate; crystal structure;
D O I
10.1016/j.inoche.2004.08.004
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reaction of tris(dihydroxyphosphonomethyl)phosphinoxide, 2,2'-bipyridyne and copper(II) chloride gave rise to the complex [Cu(2,2'-bipy){OP(CH2PO3H2)(CH2PO3H)(2)}](n), where an intricate system of hydrogen bonding interactions creates a 2D layer network. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:1113 / 1116
页数:4
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