Enzymatic synthesis of trehalose esters having lipophilicity

被引：29
|
作者：
Raku, T
Kitagawa, M
Shimakawa, H
Tokiwa, Y
机构：
[1] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058566, Japan
[2] New Energy & Ind Technol Dev Org, NEDO, Tsukuba, Ibaraki 3058566, Japan
[3] Toyobo Res Ctr, Otsu, Shiga 5200292, Japan
[4] Konan Chem Ind Co Ltd, Takatsuki, Osaka 5690066, Japan
来源：
JOURNAL OF BIOTECHNOLOGY | 2003年 / 100卷 / 03期
关键词：
trehalose ester; enzymatic synthesis; protease; regioselectivity; surface tension; biodegradability;
D O I：
10.1016/S0168-1656(02)00224-9
中图分类号：
Q81 [生物工程学（生物技术）]; Q93 [微生物学];
学科分类号：
071005 ; 0836 ; 090102 ; 100705 ;
摘要：
To improve trehalose lipophilicity, trehalose was regioselectively esterified with vinyl fatty acid esters in dimethyl formamide by protease from Bacillus subtilis to give 6-O-lauroyltrehalose, 6-O-myristoyltrehalose, 6-O-palmitoyltrehalose, 6-O-stearoyltrehalose, 6-O-oleoyltrehalose and 6-O-linoleoyltrehalose. The influence of structural variation by changing fatty acid substitute was examined by measurement of the surface tension and biodegradability. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：203 / 208
页数：6
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