Densities and surface tensions of propyl acetate plus xylenes or plus ethylbenzene from (298.15 to 308.15) K

被引:9
|
作者
Deng, Jianhong
Tan, Haifeng
Yang, Yangyi [1 ]
Zai, Shaobo
Ouyang, Gangfeng
Huang, Zhongqi
机构
[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Guangdong, Peoples R China
[2] Adm Work Safety Yantian Dist, Shenzhen 518081, Peoples R China
来源
关键词
D O I
10.1021/je060485s
中图分类号
O414.1 [热力学];
学科分类号
摘要
Densities and surface tensions for binary systems of (propyl acetate + o-xylene, + m-xylene, + p-xylene, + ethylbenzene) were measured under normal atmospheric pressure over the entire mole fraction range from (298.15 to 308.15) K. The excess molar volumes V (E) and surface tension deviations delta sigma for the above systems were calculated and fitted to the Redlich-Kister polynomial equation. The V (E) for the systems of (propyl acetate + m-xylene, + ethylbenzene) are nearly zero, but for the systems of (propyl acetate + o-xylene, + p-xylene) are negative. The delta sigma values are negative for all of the four systems. The V (E) of the four systems hardly change with increasing temperature, but their absolute values of delta sigma decrease with increasing temperature.
引用
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页码:1131 / 1135
页数:5
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