A Rapid One-Pot Synthesis of Novel High-Purity Methacrylic Phosphonic Acid (PA)-Based Polyhedral Oligomeric Silsesquioxane (POSS) Frameworks via Thiol-Ene Click Reaction

被引：9

作者：

Karuppasamy, K. ^{[1
]}

Prasanna, K. ^{[2
]}

Vikraman, Dhanasekaran ^{[1
]}

Kim, Hyun-Seok ^{[1
]}

Kathalingam, A. ^{[3
]}

Mitu, Liviu ^{[4
]}

Rhee, Hee Woo ^{[5
]}

机构：

[1] Dongguk Univ Seoul, Div Elect & Elect Engn, Seoul 04620, South Korea

[2] Kyung Hee Univ, Electrochem Energy Storage & Convers Lab EESC, 1732,Deogyeong Daero, Yongin 17104, Gyeonggi, South Korea

[3] Dongguk Univ Seoul, Millimeter Wave Innovat Technol MINT Res Ctr, Seoul 04620, South Korea

[4] Univ Pitesti, Dept Nat Sci, Pitesti 110040, Romania

[5] Sogang Univ, Polymer Mat Lab, Dept Chem & Biomol Engn, Seoul 04107, South Korea

来源：

POLYMERS | 2017年 / 9卷 / 06期

基金：

新加坡国家研究基金会;

关键词：

thiol-ene; POSS; MALDI-TOF; nanomaterials; phosphonic acid; (PH; HCP-POSS)/POLYSTYRENE PS NANOCOMPOSITES; POLYMER ELECTROLYTES; SUBSTITUENTS; CHEMISTRY;

D O I：

10.3390/polym9060192

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Herein, we demonstrate a facile methodology to synthesis a novel methacrylic phosphonic acid (PA)-functionalized polyhedral oligomeric silsesquioxanes (POSSs) via thiol-ene click reaction using octamercapto thiol-POSS and ethylene glycol methacrylate phosphate (EGMP) monomer. The presence of phosphonic acid moieties and POSS-cage structure in POSS-S-PA was confirmed by Fourier transform infrared (FT-IR) and nuclear magnetic resonance (H-1, Si-29 and P-31-NMR) analyses. Matrix-assisted laser desorption ionization time-of-flight (MALDI-TOF) mass spectrum of POSS-S-PA acquired in a dithranol matrix, which has specifically designed for intractable polymeric materials. The observed characterization results signposted that novel organo-inorganic hybrid POSS-S-PA would be an efficacious material for fuel cells as a proton exchange membrane and high-temperature applications due to its thermal stability of 380 degrees C.

引用

页数：8

共 5 条

[1] Facile "one-pot" synthesis of poly(methacrylic acid)-based hybrid monolith via thiol-ene click reaction for hydrophilic interaction chromatography
Lv, Xumei
Tan, Wangming
Chen, Ye
Chen, Yingzhuang
Ma, Ming
Chen, Bo
Yao, Shouzhuo
JOURNAL OF CHROMATOGRAPHY A, 2016, 1454 : 49 - 57
[2] Facile Synthesis and Self-Assembly of Amphiphilic Polyether-Octafunctionalized Polyhedral Oligomeric Silsesquioxane via Thiol-Ene Click Reaction
Xia, Yong
Ding, Sha
Liu, Yuejun
Qi, Zhengjian
POLYMERS, 2017, 9 (07):
[3] New sensors for the detection of picric acid: Ionic liquids based on polyhedral oligomeric silsesquioxanes prepared via a thiol-ene click reaction
Li, Wensi
Feng, Shengyu
JOURNAL OF MOLECULAR LIQUIDS, 2018, 265 : 269 - 275
[4] Preparation of polyhedral oligomeric silsesquioxane-based hybrid monolith by ring-opening polymerization and post-functionalization via thiol-ene click reaction
Liu, Zhongshan
Ou, Junjie
Lin, Hui
Wang, Hongwei
Dong, Jing
Zou, Hanfa
JOURNAL OF CHROMATOGRAPHY A, 2014, 1342 : 70 - 77
[5] Synthesis of diverse α,ω-telechelic polystyrenes with di- and tri-functionality via tandem or one-pot strategies combining aminolysis of RAFT-polystyrene and a thiol-ene "click" reaction
Zhang, Shuang-Shuang
Cui, Kun
Huang, Jin
Zhao, Qiao-Ling
Cao, Shao-Kui
Ma, Zhi
RSC ADVANCES, 2015, 5 (55): : 44571 - 44577

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