Asymmetric Si-O coupling of alcohols

被引：90

作者：

Weickgenannt, Andreas ^{[1
]}

Mewald, Marius ^{[1
]}

Oestreich, Martin ^{[1
]}

机构：

[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2010年 / 8卷 / 07期

关键词：

SILICON-STEREOGENIC SILANES; NONENZYMATIC KINETIC RESOLUTION; DONOR-FUNCTIONALIZED ALCOHOLS; ORGANOSILICON COMPOUNDS; RHODIUM COMPLEXES; STEREOSELECTIVE SILYLATION; SECONDARY ALCOHOLS; CHIRALITY TRANSFER; HYDROSILYLATION; MECHANISM;

D O I：

10.1039/b925722e

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Stereoselective Si-O couplings are auspicious processes for the synthesis of both chiral alcohols and chiral silanes. Attractive facets of this theme are currently enjoying a renaissance, and the several significant contributions are summarised in this Emerging Area.

引用

页码：1497 / 1504

页数：8

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